Published January 2004 | Version v1
Journal article Metadata-only

Synthesis and crystal structure of supramolecular compounds of tetranuclear ZrIV and HfIV aquahydroxo complexes with cucurbituril as a macrocyclic cavitand

Creators

  • 1. SO RAN, Inst. Neorganicheskoj Khimii im. A.V. Nikolaeva, Novosibirsk (Russian Federation)

Description

Slow boiling down in the air of hydrochloric solutions of zirconium(IV) and hafnium(IV) 0xychlorides with cucurbituril gave rise to formation of compounds featuring the composition [M4(OH)8(H2O)16]Cl8 · (C36H36N24O12) · 16H2O (M = Zr (1), Hf (2)). According to X-ray diffraction analysis complexes 1 and 2 are isostructural; crystal structure is a package of polymer chains built of alternating molecules of cucurbituril and four-nuclear cations [M4(OH)8(H2O)16]8+ bound via a developed system of hydrogen bonds. Compound 2 is the first example of structurally characterized four-nuclear hafnium aquacomplex

Abstract (Russian)

При медленном упаривании на воздухе солянокислых растворов оксохлоридов циркония(IV) и гафния(IV) с кукурбитурилом получены соединения состава [M4(OH)8(H2O)16]Cl8 · (C36H36N24O12) · 16H2O (M = Zr (1), Hf (2)). По данным рентгеноструктурного анализа комплексы 1 и 2 изоструктурны; кристаллическая структура представляет собой упаковку полимерных цепей, построенных из чередующихся молекул кукурбитурила и четырехъядерных катионов [M4(OH)8(H2O)16]8+, связанных за счет развитой системы водородных связей. Соединение 2 является первым примером структурно охарактеризованного четырехъядерного аквакомплекса гафния

Additional details

Additional titles

Original title (Russian)
Синтез и кристаллическая структура супрамолекулярных соединений четырехядерных аквагидроксокомплексов Зр

Publishing Information

Journal Title
Izvestiya Akademii Nauk. Rossijskaya Akademiya Nauk. Seriya Khimicheskaya
Journal Issue
no.1
Journal Page Range
p. 80-85
ISSN
1026-3500
CODEN
IASKEA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
36051980
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; BOND LENGTHS; CHEMICAL BONDS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHLORIDES; HAFNIUM COMPLEXES; HETEROCYCLIC COMPOUNDS; HYDRATES; HYDROXIDES; LATTICE PARAMETERS; MOLECULAR STRUCTURE; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; ORTHORHOMBIC LATTICES; ZIRCONIUM COMPLEXES
Descriptors DEC
CHLORINE COMPOUNDS; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIMENSIONS; HALIDES; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; LENGTH; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
31 refs., 3 figs., 2 tabs.