Published April 1982 | Version v1
Journal article

Standard thermodynamic functions of cadmium and magnesium sulfates in aqueous solutions at high temperature

  • 1. Leningradskij Tekhnologicheskij Inst. (USSR)

Description

Standard values of Gibbs energies of dissolution (δGsub(0, T)sup(E)), formation (δGsub(T)sup(0), aq) and hydration (δGsub(h)sup(0)) reactions of cadmium sulfate ions for 393-448 K are obtained. The calculated values give a good coincidence with the well-known data of calorimetric measurements. It is established that the strong interatomic interaction is present in the investigated solution, which increases with the temperature increase. The presence of association and complexing in the solution of this electrolyte is supposed

Additional details

Additional titles

Original title (Russian)
Стандартные термодинамические функции сульфатов магния и кадмия в водных растворах при высоких температурах

Publishing Information

Journal Title
Zh. Prikl. Khim.
Journal Volume
55
Journal Issue
4
Series
Zh. Prikl. Khim.
Journal Page Range
770-775
ISSN
0044-4618

Optional Information

Notes
For English translation see the journal Journal of Applied Chemistry of the USSR (USA).