Published June 28, 2008 | Version v1
Journal article

Binding energy and geometry of e+A (A=Li,Na) by the hyperspherical approach

  • 1. Graduate School of the Chinese Academy of Sciences, Beijing 100049 (China)
  • 2. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (China)
  • 3. Department of Physics, Huazhong Normal University, Wuhan 430079 (China)
  • 4. Department of Physics, Henan Normal University, XinXiang 453007 (China)

Description

We calculate the binding energy and geometry of the weakly bound e+Li and e+Na systems within the framework of hyperspherical coordinates. The Schroedinger equation in hyperangular coordinates is solved at a series of fixed hyper-radii using B-splines and the resulting coupled hyper-radial equation is solved using the slow variable discretization method developed by Tolstikhin et al. [J. Phys. B 29, L389 (1996)]. Great efforts are made in optimizing the distribution of B-splines to overcome the slow convergence of the binding energy and geometrical quantities. This approach allows us to obtain the results with improved convergence that are in good agreement with the best values reported to date. In addition, an analysis of the structure of the two systems is also made and the e+Na system is seen to exhibit quantum halo features

Additional details

Identifiers

Publishing Information

Journal Title
Journal of Chemical Physics
Journal Volume
128
Journal Issue
24
Journal Page Range
p. 244314-244314.6
ISSN
0021-9606
CODEN
JCPSA6

Optional Information

Notes
(c) 2008 American Institute of Physics