Published November 25, 2019 | Version v1
Journal article Metadata-only

Rhodium-catalyzed C−H activation enabled by an indium metalloligand

Creators

  • 1. Department of Chemistry, School of Science, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo (Japan)
  • 2. JST, PRESTO, Honcho, Kawaguchi, Saitama (Japan)

Description

Rhodium complexes with an indium metalloligand were successfully synthesized by utilizing a pyridine-tethered cyclopentadienyl ligand as a support for an In−Rh bond. The indium metalloligand dramatically changes the electronic and redox properties of the rhodium metal, thereby enabling catalysis of sp2C−H bond activation. (© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)

Availability note (English)

Available from: http://dx.doi.org/10.1002/anie.201910197

Additional details

Identifiers

DOI
10.1002/anie.201910197;

Publishing Information

Journal Title
Angewandte Chemie (International Edition)
Journal Volume
58
Journal Issue
48
Journal Page Range
p. 17251-17254
ISSN
1433-7851
CODEN
ACIEF5

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
51022817
Subject category
S36: MATERIALS SCIENCE; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CATALYSIS; CHEMICAL BONDS; DENSITY FUNCTIONAL METHOD; ELECTRONIC STRUCTURE; INDIUM COMPLEXES; LIGANDS; MOLECULAR ORBITAL METHOD; ORGANOMETALLIC COMPOUNDS; PYRIDINE; REDOX REACTIONS; RHODIUM; RHODIUM COMPLEXES; VOLTAMETRY
Descriptors DEC
AZINES; CALCULATION METHODS; CHEMICAL REACTIONS; COMPLEXES; ELEMENTS; HETEROCYCLIC COMPOUNDS; METALS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PLATINUM METALS; PYRIDINES; REFRACTORY METALS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENTS; VARIATIONAL METHODS