Published 1978 | Version v1
Journal article Metadata-only

Cocondensation reactions of uranium tetrafluoride and hexafluoride with alkali metals and alkali-metal fluorides in low-temperature argon matrices

Creators

  • 1. Rice Univ., Houston, Tex. (USA). Dept. of Chemistry

Description

The compounds UF4 and UF6, co-condensed with various alkali metals and alkali-metal fluorides, have provided i.r. spectroscopic evidence for the formation of MUF4, MUF5, MUF6, M2UF6, and MUF7 species. The bands are discussed in terms of the anion symmetry and the interactions between the alkali-metal and uranium ions. (author)

Additional details

Identifiers

DOI
10.1039/dt9780000433;

Publishing Information

Journal Title
Journal of the Chemical Society, Dalton Transactions
Journal Issue
5
Series
J. Chem. Soc. (London), Dalton Trans.
Journal Page Range
433
ISSN
0300-9246

INIS

Country of Publication
United Kingdom
Country of Input or Organization
United Kingdom
INIS RN
9394457
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ARGON; CESIUM; CESIUM FLUORIDES; CHEMICAL PREPARATION; CHEMICAL REACTIONS; HIGH VACUUM; INFRARED SPECTRA; IONS; LITHIUM; LITHIUM 6; LITHIUM 7; MOLECULAR STRUCTURE; POTASSIUM FLUORIDES; SODIUM; SODIUM FLUORIDES; ULTRALOW TEMPERATURE; URANIUM HEXAFLUORIDE; URANIUM TETRAFLUORIDE
Descriptors DEC
ACTINIDE COMPOUNDS; ALKALI METAL COMPOUNDS; ALKALI METALS; CESIUM COMPOUNDS; CHARGED PARTICLES; ELEMENTS; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; ISOTOPES; LIGHT NUCLEI; LITHIUM ISOTOPES; METALS; NONMETALS; NUCLEI; ODD-EVEN NUCLEI; ODD-ODD NUCLEI; POTASSIUM COMPOUNDS; RARE GASES; SODIUM COMPOUNDS; SPECTRA; STABLE ISOTOPES; SYNTHESIS; URANIUM COMPOUNDS; URANIUM FLUORIDES

Optional Information

Notes
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