Published December 2017 | Version v1
Journal article Metadata-only

Heat capacity and thermodynamic functions of thulium orthophosphate TmPO4 in the range of 10–1350 K

Creators

  • 1. Russian Academy of Sciences, Kurnakov Institute of General and Inorganic Chemistry (Russian Federation)
  • 2. Russian Academy of Sciences, Vernadsky Institute of Geochemistry and Analytical Chemistry (Russian Federation)

Description

The heat capacity of TmPO4 in temperature ranges of 9.11–346.05 and 304.6–1344.6 K is measured via adiabatic and differential scanning calorimetry, respectively. The measurement data are used to calculate the temperature dependences of the heat capacity, entropy, change in enthalpy, and reduced Gibbs energy of TmPO4 in the range of 10–1344 K. The Gibbs energy of formation of thulium orthophosphate from elements ΔfG0(298.15 K) is determined.

Additional details

Identifiers

DOI
10.1134/S003602441711019X;

Publishing Information

Journal Title
Russian Journal of Physical Chemistry
Journal Volume
91
Journal Issue
12
Journal Page Range
p. 2310-2316
ISSN
0036-0244
CODEN
RJPCAR

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
51034071
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CALORIMETRY; ENTHALPY; ENTROPY; PHOSPHATES; SPECIFIC HEAT; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE; THERMODYNAMICS; THULIUM
Descriptors DEC
ELEMENTS; METALS; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; PHYSICAL PROPERTIES; RARE EARTHS; THERMODYNAMIC PROPERTIES

Optional Information

Copyright
Copyright (c) 2017 Pleiades Publishing, Ltd.