Published August 1981 | Version v1
Journal article Metadata-only

Synthesis and NMR study of solid electrolytes in the system Li3N-LiCl

Creators

  • 1. Osaka Univ., Suita (Japan). Inst. of Scientific and Industrial Research
  • 2. Government Industrial Research Inst., Osaka, Ikeda (Japan)

Description

Syntheses have been carried out in the whole range of the system Li3N-LiCl. The cubic antifluorite type structure is possessed in the composition range 2Li3N-3LiCl-9Li3N.11LiCl. Other than these, the new phase Li9N2Cl3 was found which did not crystallize in the cubic system. The 7Li relaxation was studied for the antifluorite-type compounds and for the Li11N3Cl2. The activation energies for the Li+ hopping motion were obtained: Esub(a) = 0.19-0.21 eV for the cubic compounds, and 0.33 eV for the Li11N3Cl2. The ionic conductivities for all compounds were measured using the pulsed current method. The new phase of Li9N2Cl3 showed the highest ionic conductivity in this series of compounds. (Auth.)

Additional details

Publishing Information

Journal Title
Solid State Ionics
Journal Issue
3-4
Series
Solid State Ionics.

Conference

Title
3. International meeting on solid electrolytes - solid state ionics and galvanic cells.
Dates
15 - 19 Sep 1980.
Place
Tokyo, Japan.

INIS

Country of Publication
Netherlands
Country of Input or Organization
Netherlands
INIS RN
13670107
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Resource subtype / Literary indicator
Conference, Numerical Data
Descriptors DEI
ACTIVATION ENERGY; EXPERIMENTAL DATA; IONIC CONDUCTIVITY; LITHIUM CHLORIDES; LITHIUM IONS; LITHIUM NITRIDES; LITHIUM 7; NUCLEAR MAGNETIC RESONANCE; RELAXATION TIME; SELF-DIFFUSION; SOLID ELECTROLYTES; SPIN-LATTICE RELAXATION; SPIN-SPIN RELAXATION; SYNTHESIS
Descriptors DEC
ALKALI METAL COMPOUNDS; ATOMIC IONS; CHARGED PARTICLES; CHLORIDES; CHLORINE COMPOUNDS; DATA; DIFFUSION; ELECTRIC CONDUCTIVITY; ELECTRICAL PROPERTIES; ELECTROLYTES; ENERGY; HALIDES; HALOGEN COMPOUNDS; INFORMATION; IONS; ISOTOPES; LIGHT NUCLEI; LITHIUM COMPOUNDS; LITHIUM HALIDES; LITHIUM ISOTOPES; MAGNETIC RESONANCE; NITRIDES; NITROGEN COMPOUNDS; NUCLEI; NUMERICAL DATA; ODD-EVEN NUCLEI; PHYSICAL PROPERTIES; RELAXATION; RESONANCE; STABLE ISOTOPES