Published May 1996
| Version v1
Journal article
Reaction of monocyclopentadienyl complexes of uranium(4) with oxygen
Description
Uranium complexes of the composition CpUCl3 x 2L[Cp=eta5-C5H5, L=C4H8O (THF), (C4H9O)3PO(TBP)] interact with molecular oxygen at 298 K in organic solvents with formation of uranyl dichloride complexes UO2Cl2 x 2L and isolation of cyclopentadiene. The latter is easily halogenized under the reaction conditions up to a polymeric product. Probable routes of the cyclopentadienyl ligand transformation are suggested. Refs. 9, refs. 3, tabs. 2
Additional details
Additional titles
- Original title (Russian)
- Реакция моноциклопентадиенильных комплексов урана(4) с кислородом
Publishing Information
- Journal Title
- Zhurnal Obshchej Khimii
- Journal Volume
- 66
- Journal Issue
- 128
- Journal Page Range
- p. 721-724.
- ISSN
- 0044-460X
- CODEN
- ZOKHA4
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 28000120
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- ABSORPTION SPECTRA; CHEMICAL REACTION KINETICS; CHLORIDES; CYCLOPENTADIENE; INFRARED SPECTRA; ORGANIC SOLVENTS; OXIDATION; OXYGEN; TBP; TEMPERATURE RANGE 0273-0400 K; TETRAHYDROFURAN; ULTRAVIOLET SPECTRA; URANIUM COMPLEXES
- Descriptors DEC
- ACTINIDE COMPLEXES; ALKENES; BUTYL PHOSPHATES; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COMPLEXES; CYCLOALKENES; DIENES; ELEMENTS; ESTERS; FURANS; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; KINETICS; NONAQUEOUS SOLVENTS; NONMETALS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; PHOSPHORIC ACID ESTERS; POLYENES; REACTION KINETICS; SOLVENTS; SPECTRA; TEMPERATURE RANGE