Published August 31, 1977 | Version v1
Journal article Metadata-only

Application of deuterium magnetic resonance to biosynthetic studies. 1. Biosynthesis of ovalicin

Creators

  • 1. Brown Univ., Providence

Description

Deuterium nuclear magnetic resonance was used to distinguish among various mechanisms for the oxidative cleavage of bergamotene to the o-mentane framework of ovalicin. In addition the deuteration positions were determined in biosynthesized ovalicin. The experimental results showed the utility of deuterium NMR as a biosynthetic tool

Additional details

Identifiers

DOI
10.1021/ja00460a065;

Publishing Information

Journal Title
Journal of the American Chemical Society
Journal Volume
99
Journal Issue
18
Series
J. Am. Chem. Soc.
Journal Page Range
6132-6134
ISSN
0002-7863

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
9365464
Subject category
S62: RADIOLOGY AND NUCLEAR MEDICINE;
Descriptors DEI
ANTIBIOTICS; BIOCHEMICAL REACTION KINETICS; BIOSYNTHESIS; DEUTERIUM; NUCLEAR MAGNETIC RESONANCE; TRACER TECHNIQUES
Descriptors DEC
DRUGS; HYDROGEN ISOTOPES; ISOTOPE APPLICATIONS; ISOTOPES; KINETICS; LIGHT NUCLEI; MAGNETIC RESONANCE; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; REACTION KINETICS; RESONANCE; STABLE ISOTOPES; SYNTHESIS

Optional Information

Notes
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