Published May 1981
| Version v1
Journal article
Complexes of dioxocyanogen (OCN)2 with TiCl4 and ZrCl4
Description
A solution of (OCN)2 was obtained by reaction of AgOCN with Br2 in H2CCl2 at -70 0C. From this the complexes TiCl4(NCO)2 and ZrCl4(NCO)2 were obtained by addition of equimolar amounts of TiCl4 and ZrCl4, respectively. According to the i.r. and Raman spectra, the (NCO)2 ligand is bonded via its N atoms to the metal. (author)
Additional details
Additional titles
- Original title (German)
- Die Komplexe von Dioxocyan (OCN)
Publishing Information
- Journal Title
- Z. Anorg. Allg. Chem.
- Journal Volume
- 476
- Series
- Z. Anorg. Allg. Chem.
- Journal Page Range
- 149-152
- ISSN
- 0044-2313
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- German Democratic Republic
- INIS RN
- 12637440
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL PREPARATION; CYANATES; INFRARED SPECTRA; MOLECULAR STRUCTURE; RAMAN SPECTRA; ZIRCONIUM CHLORIDES; ZIRCONIUM COMPLEXES
- Descriptors DEC
- CARBONIC ACID DERIVATIVES; CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS; ZIRCONIUM COMPOUNDS