A Review on Additives-assisted Ultrasound for Organic Pollutants Degradation

Highlights: • Factors influencing the pollutants degradation in US alone are summarized and discussed. • The synergistic effect of US and various additives are reviewed. • Reaction mechanisms of additives assisted ultrasound for pollutants degradation are elucidated. • The challenges and some research needs of SAOPs are proposed. In the past 2 decades, considerable attentions have been paid to the sonochemical advanced oxidation processes (SAOPs) in the fields of pollutants removal. SAOPs are powerful methods for refractory pollutants degradation due to the free radicals (e.g., • OH and • H) generated by water pyrolysis and extremely high temperature and pressure in and around cavitation bubbles. Reports on various additives for the improvement of sonochemical pollutants degradation including oxidants, inorganic anions, etc. have been made. This paper presents a comprehensive review on the ultrasound (US) alone and sono-hybrid systems for various pollutants degradation. In this paper, the degradation efficiency of various pollutants in sono-hybrid systems are elucidated in detail, and particular emphasis is placed on the reaction mechanism of additives in US for the enhancement of pollutants degradation. The problems on the applications of the current sono-hybrid systems are identified and discussed, and the outlooks for further in-depth studies on the challenges and some research needs for the applications of SAOPs for the removal of organic pollutants from aquatic systems are made at the end.