Published 1995 | Version v1
Journal article Metadata-only

Crystal ad molecular structure of tetra technetium tricarbonyliodide [Tc(CO)3I]4

Creators

  • 1. RAN, Moscow (Russian Federation). Inst. Fizicheskoj Khimii

Description

X-ray investigation into [Tc(CO)3I]4 monocrystal was carried out. Crystals belong to monoclinic syngony, a=18.125 (12), b=9.741 (6), c=16.577 (9) A, β=118.50 (4) deg, V=2572 (3) A3, C2/c space group, Z=4, dded.=3.191 g/cm3, μ(MoKα)=67 cm-1. Single tetramerous molecules-[Tc(CO)3I]4, characterized by cube-shaped structure form the crystal structure. Tc(CO)3 fragments are linked between one another by iodide cross-linkages. 5 refs., 2 figs., 3 tabs

Additional details

Additional titles

Original title (Russian)
Кристаллическая и молекулярная структура тетрамерного трикарбонилиодида технеция [Тc(CO)

Publishing Information

Journal Title
Radiokhimiya
Journal Volume
37
Journal Issue
3
Journal Page Range
p. 193-195.
ISSN
0033-8311
CODEN
RADKAU

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
27050466
Subject category
S36: MATERIALS SCIENCE; S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
BOND ANGLE; BOND LENGTHS; CARBONYLS; DENSITY; IODIDES; LATTICE PARAMETERS; MOLECULAR STRUCTURE; MONOCLINIC LATTICES; MONOCRYSTALS; SPACE GROUPS; TECHNETIUM COMPLEXES
Descriptors DEC
COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; HALIDES; HALOGEN COMPOUNDS; IODINE COMPOUNDS; PHYSICAL PROPERTIES; SYMMETRY GROUPS; TRANSITION ELEMENT COMPLEXES