Published September 1996 | Version v1
Journal article Metadata-only

Crystal structure of tetrahydrate hexamethylenediammonium pentafluorohafnate

Creators

  • 1. AN SSSR, Chernogolovka (Russian Federation). Otdelenie Inst. Khimicheskoj Fiziki

Description

Crystal structure of (C6N2H18)(HfF5)2x4H2O(1), formed by bridge dimer complex anions [Hf2F10(H-2O)2]2-, cations [NH3(CH2)6NH3]2+ and crystallization water molecules, has been ascertained. Coordination polyhedron of Hf is a slightly distorted pentagonal bipyramid, one of its equatorial plane vertices being occupied by coordinated molecule of H2O, the rest vertices by F atoms. Via common equatorial rib F-F the Hf polyhedrons join in dimers. The crystals of 1 belong to monoclinic crystal system, sp.gr. P21/n. Unit cell parameters are as follows: a=8.853(3), b=7.874(3), c=13.149(5)A, beta=92.07(3), d(calcldi)=2.67. Refs. 7, figs. 3, tabs. 3

Additional details

Additional titles

Original title (Russian)
Кристаллическая структура тетрагидрата пентафторогафната гексаметилендиаммония

Publishing Information

Journal Title
Koordinatsionnaya Khimiya
Journal Volume
22
Journal Issue
9
Journal Page Range
p. 677-681.
ISSN
0132-344X
CODEN
KOKHDC

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
28033094
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; CHEMICAL BONDS; FLUORIDES; HAFNIUM COMPLEXES; HYDRATES; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MONOCLINIC LATTICES; QUATERNARY COMPOUNDS; SPACE GROUPS
Descriptors DEC
AMINES; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DISTANCE; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; ORGANIC COMPOUNDS; SYMMETRY GROUPS; TRANSITION ELEMENT COMPLEXES