Published November 1, 2013 | Version v1
Journal article Metadata-only

Surface modification of zinc-containing hydroxyapatite by tartaric acid

Creators

  • 1. Laboratoire de Physico-Chimie des Matériaux, Faculté des Sciences de Monastir, 5019 Monastir (Tunisia)
  • 2. Laboratoire Charles Coulomb, UMR 5221 CNRS/UM2, Université Montpellier 2, Place E. Bataillon, 34095 Montpellier (France)
  • 3. Institut Préparatoire aux Etudes d'Ingénieur de Monastir (Tunisia)

Description

The surface of Zn-substituted hydroxyapatites (Ca(10−x)Znx(PO4)6(OH)2, with 0 ≤ x ≤ 2, CaxZnxHA) modified by tartaric acid was investigated by various techniques. XRD powder patterns revealed that synthesized samples were single phase of HA with broadened XRD reflections. FTIR and (13C, 1H and 31P) MAS NMR measurements confirmed the grafting of the tartaric acid on the apatite surface. Chemical analysis showed that for ZnHA the grafted acid amount increases with the increase of the acid concentration in the starting solutions, while for HA, it remained constant, indicating more reactivity for ZnHA surface. A mechanism of surface modification is proposed based on the obtained results.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.apsusc.2013.07.006

Additional details

Identifiers

DOI
10.1016/j.apsusc.2013.07.006;
PII
S0169-4332(13)01303-2;

Publishing Information

Journal Title
Applied Surface Science
Journal Volume
284
Journal Page Range
p. 66-71
ISSN
0169-4332
CODEN
ASUSEE

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
46003707
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Descriptors DEI
APATITES; CARBON 13; CHEMICAL ANALYSIS; FOURIER TRANSFORM SPECTROMETERS; HYDROGEN 1; INFRARED SPECTRA; MODIFICATIONS; NUCLEAR MAGNETIC RESONANCE; PHOSPHATES; PHOSPHORUS 31; POWDERS; REACTIVITY; REFLECTION; SURFACES; TARTARIC ACID; X-RAY DIFFRACTION; ZINC
Descriptors DEC
CARBON ISOTOPES; CARBOXYLIC ACIDS; COHERENT SCATTERING; DIFFRACTION; ELEMENTS; EVEN-ODD NUCLEI; HYDROGEN ISOTOPES; HYDROXY ACIDS; ISOTOPES; LIGHT NUCLEI; MAGNETIC RESONANCE; MEASURING INSTRUMENTS; METALS; MINERALS; NUCLEI; ODD-EVEN NUCLEI; ORGANIC ACIDS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHATE MINERALS; PHOSPHORUS COMPOUNDS; PHOSPHORUS ISOTOPES; RESONANCE; SCATTERING; SPECTRA; SPECTROMETERS; STABLE ISOTOPES

Optional Information

Copyright
Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.