Published December 15, 1981 | Version v1
Journal article Metadata-only

Effect of deuteration upon the tunneling rotation of a hindered methyl group in x-irradiated 2,2-dimethyl-d6-5-methyl-1,3-dioxane-4,6-dione crystals: An ENDOR study

Creators

  • 1. Department of Chemical Physics, University of Geneva, 1211 Geneva, Switzerland

Description

ENDOR studies are reported of the effect of deuteration on the tunneling rotational frequency of a hindered methyl group in x-irradiated 2,2,5-trimethyl-1,3-dioxane-4,6,-dione. The radical structure is discussed

Additional details

Publishing Information

Journal Title
J. Chem. Phys.
Journal Volume
75
Journal Issue
12
Series
J. Chem. Phys.
Journal Page Range
5963-5964
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
13668029
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
DEUTERATION; ELECTRON SPIN RESONANCE; ENDOR; ORGANIC OXYGEN COMPOUNDS; RADICALS; RADIOLYSIS; ROTATIONAL STATES; X RADIATION
Descriptors DEC
CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; ENERGY LEVELS; EXCITED STATES; IONIZING RADIATIONS; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; RADIATION EFFECTS; RADIATIONS; RESONANCE