Thermogravimetric studies of (U0.72Ce0.28)O2.00 under different oxygen partial pressures
- 1. Fuel Chemistry Division, Bhabha Atomic Research Centre, Mumbai (India)
Description
(U, Pu)O2 mixed oxide fuels with different percent of plutonium have been developed and used all over the world in commercial and research reactors. (U0.72Pu0.28)O2.00 is used as a nuclear fuel in Prototype Fast Breeder Reactor (PFBR) at Kalpakkam. CeO2 has been used as a surrogate for PuO2 because of similarity in their thermophysical and thermochemical properties. In addition, cerium is one of the high yield fission products formed during burn up and dissolves in UO2 matrix to form (U, Ce)O2. It is reported that the oxidation and phase behavior of (U1-yCey)O2±x system are quite comparable to (U1-yPuy)O2±x system in hyper-stoichiometric (2+x) region than in hypo-stoichiometric (2-x) region. (U0.72Ce0.28)O2 was prepared by gel combustion route followed by sintering at 1400°C for 10 h in Ar/8%H2 atmosphere
Additional details
Publishing Information
- Publisher
- Indian Thermal Analysis Society
- Imprint Place
- Mumbai (India)
- Imprint Title
- Proceedings of the twentieth DAE-BRNS symposium on thermal analysis: book of abstracts
- Imprint Pagination
- 448 p.
- Journal Page Range
- p. 101
Conference
- Title
- 20. DAE-BRNS symposium on thermal analysis
- Acronym
- THERMANS-2016
- Dates
- 18-20 Jan 2016
- Place
- Varanasi (India)
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 47076181
- Subject category
- S11: NUCLEAR FUEL CYCLE AND FUEL MATERIALS;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- MIXED OXIDE FUELS; PLUTONIUM OXIDES; THERMAL GRAVIMETRIC ANALYSIS; URANIUM OXIDES; X-RAY DIFFRACTION
- Descriptors DEC
- ACTINIDE COMPOUNDS; CHALCOGENIDES; CHEMICAL ANALYSIS; COHERENT SCATTERING; DIFFRACTION; ENERGY SOURCES; FUELS; GRAVIMETRIC ANALYSIS; MATERIALS; NUCLEAR FUELS; OXIDES; OXYGEN COMPOUNDS; PLUTONIUM COMPOUNDS; QUANTITATIVE CHEMICAL ANALYSIS; REACTOR MATERIALS; SCATTERING; SOLID FUELS; THERMAL ANALYSIS; TRANSURANIUM COMPOUNDS; URANIUM COMPOUNDS
Optional Information
- Notes
- 1 ref., 2 figs.