Published November 1989 | Version v1
Journal article Metadata-only

Reactions of metallocluster thiocomplexes of molybdenum (NH4)2Mo2S12 · 2H2O and (NH4)2Mo3S13 · 2H2O with chlorine and bromine

Creators

  • 1. AN SSSR, Novosibirsk (USSR). Inst. Neorganicheskoj Khimii

Description

Binuclear (NH4)2Mo2S12 · 2H2O and three-nuclear (NH4)2Mo3S13 · 2H2O thiocomplexes interact with chlorine and bromine in acetonitrile. The [Mo2(μ2-S2)2]6+ and [Mo3(μ3-S) · (μ2-S2)3]4+ fragments of the basic thiocomplexes are preserved at that. Conditions of preparing thiohalide complexes (Et4N)2Mo2S4Br8, (Et4N)2Mo3S7Br6, (NH4)2Mo2S4Cl8 and (NH4)2Mo3S7Cl6 · 2H2O with high yields were found. Complexes were characterized by IR and Raman spectra

Additional details

Additional titles

Original title (Russian)
Реакции металлокластерных тиокомплексов молибдена (NH

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
34
Journal Issue
11
Series
Zh. Neorg. Khim.
Journal Page Range
2984-2987
ISSN
0044-457X
CODEN
ZNOKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
21081997
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMMONIUM COMPOUNDS; BROMIDES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; CHLORIDES; HYDRATES; INFRARED SPECTRA; MEDIUM TEMPERATURE; MOLECULAR STRUCTURE; MOLYBDENUM COMPLEXES; RAMAN SPECTRA; STABILITY; SULFIDES
Descriptors DEC
BROMINE COMPOUNDS; CHALCOGENIDES; CHLORINE COMPOUNDS; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; SPECTRA; SULFUR COMPOUNDS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES