Published August 2005 | Version v1
Journal article

Studies on thermo-acoustic parameters in binary liquid mixtures of phosphinic acid (Cyanex 272) with different diluents at temperature 303.15 K: an ultrasonic study

  • 1. Department of Chemistry, Utkal University, Bhubaneswar 751004 (India)
  • 2. Eastern Academy of Science and Technology, Phulnakhara, Khurda 754001 (India)

Description

Acoustical investigations for the binary mixtures of phosphinic acid (Cyanex 272), used as liquid-liquid extractant, have been made in various diluents such as benzene, toluene, and xylene from ultrasonic velocity and density measurements at temperature 303.15 K and atmospheric pressure. This study involves evaluation of different thermo-acoustic parameters along with the excess properties, which are interpreted in the light of molecular interaction between a polar extractant, Cyanex 272 with non-polar diluent, benzene and weakly polar diluents, toluene and xylene. The excess values are correlated using Redlich-Kister polynomial equation, and corresponding adjustable parameters are derived

Additional details

Identifiers

DOI
10.1016/j.jct.2004.12.001;
PII
S0021-9614(04)00271-X;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
37
Journal Issue
8
Journal Page Range
p. 820-825
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.