Published August 2005
| Version v1
Journal article
Studies on thermo-acoustic parameters in binary liquid mixtures of phosphinic acid (Cyanex 272) with different diluents at temperature 303.15 K: an ultrasonic study
- 1. Department of Chemistry, Utkal University, Bhubaneswar 751004 (India)
- 2. Eastern Academy of Science and Technology, Phulnakhara, Khurda 754001 (India)
Description
Acoustical investigations for the binary mixtures of phosphinic acid (Cyanex 272), used as liquid-liquid extractant, have been made in various diluents such as benzene, toluene, and xylene from ultrasonic velocity and density measurements at temperature 303.15 K and atmospheric pressure. This study involves evaluation of different thermo-acoustic parameters along with the excess properties, which are interpreted in the light of molecular interaction between a polar extractant, Cyanex 272 with non-polar diluent, benzene and weakly polar diluents, toluene and xylene. The excess values are correlated using Redlich-Kister polynomial equation, and corresponding adjustable parameters are derived
Additional details
Identifiers
- DOI
- 10.1016/j.jct.2004.12.001;
- PII
- S0021-9614(04)00271-X;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 37
- Journal Issue
- 8
- Journal Page Range
- p. 820-825
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 37024638
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ATMOSPHERIC PRESSURE; BENZENE; BINARY MIXTURES; DENSITY; EQUATIONS; EVALUATION; INTERACTIONS; LIQUIDS; PHOSPHINIC ACIDS; POLYNOMIALS; SOLVENTS; TEMPERATURE RANGE 0273-0400 K; TOLUENE; XYLENES
- Descriptors DEC
- ALKYLATED AROMATICS; AROMATICS; DISPERSIONS; FLUIDS; FUNCTIONS; HYDROCARBONS; MIXTURES; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; PHYSICAL PROPERTIES; TEMPERATURE RANGE
Optional Information
- Copyright
- Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.