Hierarchically structured ternary heterojunctions based on Ce3+/ Ce4+ modified Fe3O4 nanoparticles anchored onto graphene oxide sheets as magnetic visible-light-active photocatalysts for decontamination of oxytetracycline

Highlights: • Magnetite was promoted by Ce and CeO₂, and anchored onto graphene oxide sheets. • The prepared nanocomposites were evaluated for photocatalytic degradation of OTC. • Fe_2.8Ce_0.2O₄/GO nanocomposite displayed great photo-activity in the visible region. • Degradation byproducts of OTC were identified, and a pathway was proposed. • The mechanism of the OTC photodegradation over Fe_2.8Ce_0.2O₄/GO is described. -- Abstract: The main prerequisite of an active visible-light-driven photocatalyst is to effectively utilize the visible light to induce electron-hole (e⁻/h⁺) pairs of expanded lifetime. To this end, for the first time, the ternary heterojunctions of CeO₂/Fe₃O₄ /Graphene oxide and Ce³⁺/ Fe₃O₄ /Graphene oxide (CeO₂/Fe₃O₄/GO and Fe_2.8Ce_0.2O₄/GO) were prepared via facile ultrasonic-assisted procedures and employed for destruction of oxytetracycline (OTC) under visible light irradiation. The changes in the relative crystal structure, morphology, atomic and surface functional group composition, magnetic, and optic properties of magnetite were uncovered by various techniques. The substantial degradation and mineralization of OTC via visible light/Fe_2.8Ce_0.2O₄/GO system were thoroughly discussed in terms of narrowed band gap energy, the principal function of Ce³⁺/Ce⁴⁺ and Fe²⁺/Fe³⁺ redox pairs and GO platelets, enhanced charge separation and transfer, and enlarged active surface area. Furthermore, the performance of visible light/Fe_2.8Ce_0.2O₄/GO system was evaluated for treating real wastewater and its efficiency was investigated using a number of enhancers and scavengers. Finally, the generated byproducts in the course of photodegradation were determined and the oxidation pathway, photocatalytic kinetics, and plausible mechanism were proposed. The results confirmed that the introduced Ce ions and graphene oxide sheets boost the photo-catalytic efficiency of magnetite for photodegradation of OTC.