Published August 2003 | Version v1
Journal article Metadata-only

Trinuclear metal chelates of β-aminovinylimines

Creators

  • 1. Rostovskij Gosudarstvennyj Univ., Rostov-na-Donu (Russian Federation)
  • 2. Rostovskij Gosudarstvennyj Univ., Nauchno-Issledovatel'skij Inst. Fizicheskoj i Organicheskoj Khimii, Rostov-na-Donu (Russian Federation)

Description

Trinuclear metal chelates of β-aminovinylimines of the composition M3L2 (M = Cd, Cu, Ni, Co, Zn; L = bisazomethyn on the basis of nitro- or phenylmalonic dialdehyde) were prepared using chemical and electrochemical methods of synthesis. The products were characterized by the methods of elementary analysis, 1H NMR and IR spectroscopy. Results of spectral studies confirmed chelate structure of cadmium and zinc trinuclear complexes

Abstract (Russian)

С помощью химического и электрохимического методов синтеза получены трехъядерные металлохелаты β-аминовинилиминов состава M3L2 (M = Cd, Cu, Ni, Co, Zn; L = бисазометин на основе нитро- или фенилмалонового диальдегида). Продукты охарактеризованы методами элементного анализа, ЯМР 1Н и ИК спектроскопии. Результаты спектральных исследований подтвердили хелатное строение трехъядерных комплексов кадмия и цинка

Additional details

Additional titles

Original title (Russian)
Трехьядерные металлохелаты β-аминовинилиминов

Publishing Information

Journal Title
Zhurnal Obshchej Khimii
Journal Volume
73
Journal Issue
8
Journal Page Range
p. 1261-1268
ISSN
0044-460X
CODEN
ZOKHA4

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
36052188
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AROMATICS; CADMIUM COMPLEXES; CHELATES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; IMINES; INFRARED SPECTRA; MOLECULAR STRUCTURE; NMR SPECTRA; PROTONS
Descriptors DEC
BARYONS; COMPLEXES; ELEMENTARY PARTICLES; FERMIONS; HADRONS; NUCLEONS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SPECTRA; SYNTHESIS

Optional Information

Notes
36 refs., 3 tabs.