Published July 1991
| Version v1
Journal article
Kinetic analysis and mechanism of isothermal annealing of cobalt neutron capture recoil in pure K3Co(SCN)6 and in K3Co(SCN)6-K3Cr(SCN)6, K3Co(SCN)6-K3Fe(SCN)6 mixed crystals
Description
The annealing data have been analyzed according to the models developed by Fletcher-Brown and by Vand-Primak to deduce the kinetic behaviour. The results have been discussed in terms of retention and non retention reactions and from the view points of a kinetic model and a mechanism involving isotopic exchange, ligand and metal vacancy exchange, substitution and transfer reactions. 16 refs
Additional details
Publishing Information
- Journal Title
- Bulletin de la Societe Chimique de France
- Journal Volume
- 128
- Journal Issue
- 4
- Series
- Bull. Soc. Chim. Fr.
- Journal Page Range
- 435-437
- ISSN
- 0037-8968
- CODEN
- BSCFA
INIS
- Country of Publication
- France
- Country of Input or Organization
- France
- INIS RN
- 23010621
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- ANNEALING; CHROMIUM COMPLEXES; COBALT COMPLEXES; HOT ATOM CHEMISTRY; IRON COMPLEXES; ISOTOPIC EXCHANGE; KINETICS; LIGANDS; POTASSIUM COMPOUNDS; RECOILS; THIOCYANATES
- Descriptors DEC
- ALKALI METAL COMPOUNDS; ANTITHYROID DRUGS; CARBONIC ACID DERIVATIVES; CHEMISTRY; COMPLEXES; DRUGS; HEAT TREATMENTS; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; RADIOCHEMISTRY; TRANSITION ELEMENT COMPLEXES