Published 1995 | Version v1
Journal article Metadata-only

Cluster chemistry. Part 99; An unusual hydrocarbon-cluster bonding mode in Ru3 (μ3-2 η1, 2η3 - C14H17Me) (μ-CO) (CO)7, obtained from Ru3 (CO)12 and 1,5,9 - Trimethylcyclododeca - 1,5,9-triene

Creators

  • 1. Adelaide Univ., SA (Australia)
  • 2. Western Australia Univ., Nedlands, WA (Australia). Dept. of Chemistry

Description

A reaction between Ru3(CO)12 and 1,5,9-trimethylcyclododeca-1,5,9-trine has given the orange-red complex Ru3(μ3-2η1, 2η3-C14H17Me)(μ-CO)(CO)7, fully characterized by a single-crystal X-ray study. The hydrocarbon is attached to an irregular closed Ru3 cluster by two Ru-C σ-bonds and two η-allylic systems, the latter involving exocyclic CH2 and CH groups. The preparation of Ru3 (μ-H) (μ3-C12H15) (μ-dppm) (CO)7 is also reported. 10 refs., 2 tabs., 1 fig., ills

Additional details

Publishing Information

Journal Title
Australian Journal of Chemistry
Journal Volume
48
Journal Issue
9
Journal Page Range
p. 1651-1657.
ISSN
0004-9425
CODEN
AJCHAS

INIS

Country of Publication
Australia
Country of Input or Organization
Australia
INIS RN
27010028
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
CRYSTALLOGRAPHY; EXPERIMENTAL DATA; HYDROCARBONS; MONOCLINIC LATTICES; NMR SPECTRA; ORGANIC COMPOUNDS; RUTHENIUM COMPLEXES; STRUCTURAL CHEMICAL ANALYSIS; SYNTHESIS; X-RAY DIFFRACTION
Descriptors DEC
COHERENT SCATTERING; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DATA; DIFFRACTION; INFORMATION; NUMERICAL DATA; SCATTERING; SPECTRA; TRANSITION ELEMENT COMPLEXES