Published 1978 | Version v1
Journal article

Physicochemical study of high-temperature interaction between Ca2Nb2O7 and La3NbO7

  • 1. Leningradskij Tekhnologicheskij Inst. (USSR)

Description

Phase equilibria are studied in the system Ca2Nb2O7-La3NbO7 in the 1300 deg C - m.p. range. The existence is established of pyrochlore-type compound of composition Casub(4/3)LaNbsub(5/3)Osub(7) and of solid solutions on its basis cubic and rhombic-distorted in the concentration range of La3NbO7 from 33 to 90 mol% and of solid solution on the basis of La3NbO7 of the type of fluorite derivative in the 90-100 mol% range of La3NbO7. The properties of solid solutions (structure parameters, density, refractive indexes) vary with the composition

Additional details

Additional titles

Original title (Russian)
Физико-химическое исследование высокотемпературного взаимодействия CaNb

Publishing Information

Journal Title
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol.
Journal Volume
21
Journal Issue
5
Series
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol.
Journal Page Range
633-636