Published September 2016 | Version v1
Journal article Metadata-only

Synthesis, characterization and single crystal x-ray analysis of a complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine

Creators

  • 1. University of Jammu, Department of Chemistry (India)
  • 2. Department of Physics and Electronics, University of Jammu, X-ray Crystallographic Laboratory (India)

Description

Complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine [((2,4- (CH3)2C6H3O)2PS2)2Fe(NC5H4(C2H5)-4)2] is synthesized and characterized by elemental analysis, magnetic moment, IR spectroscopy and single crystal X-ray analysis. Complex crystallizes in the monoclinic sp. gr. P21/n, Z = 2. Crystal structure consists of mononuclear units with Fe(II) ion chelated by four S atoms of the two diphenyldithiophosphate ligands in bidentate manner. N atoms from two 4-ethylpyridine ligands are axially coordinated to the Fe(II) atom leading to an octahedral geometry.

Additional details

Identifiers

DOI
10.1134/S1063774516050126;

Publishing Information

Journal Title
Crystallography Reports
Journal Volume
61
Journal Issue
5
Journal Page Range
p. 810-814
ISSN
1063-7745
CODEN
CYSTE3

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
48093989
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Descriptors DEI
ATOMS; CHELATES; INFRARED SPECTRA; IRON; LIGANDS; MAGNETIC MOMENTS; MONOCLINIC LATTICES; MONOCRYSTALS; SYNTHESIS; X RADIATION
Descriptors DEC
COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; ELECTROMAGNETIC RADIATION; ELEMENTS; IONIZING RADIATIONS; METALS; RADIATIONS; SPECTRA; THREE-DIMENSIONAL LATTICES; TRANSITION ELEMENTS

Optional Information

Copyright
Copyright (c) 2016 Pleiades Publishing, Inc.