Published December 14, 1978 | Version v1
Journal article

Rate constants for self- and cross-termination of transient radicals by modulation electron spin resonance spectroscopy

Creators

  • 1. Notre Dame Univ., IN

Description

A spectroscopic technique is described which allows an analysis of the kinetics of systems with two kinds of species present. Equations are presented for the rate constants for formation of the two species. The results of experimental tests of the equations with data from aqueous solutions containing diglycolic acid and acetone irradiated with uv radiation in the cavity of the ESR spectrometer are presented. The experimental data generally agreed with the values predicted from the equations

Additional details

Publishing Information

Journal Title
J. Phys. Chem.
Journal Volume
82
Journal Issue
25
Series
J. Phys. Chem.
Journal Page Range
2754-2756
ISSN
0022-3654

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
10472455
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
No Abstract
Descriptors DEI
ACETONE; ELECTRON SPIN RESONANCE; GLYCOLIC ACID; PHOTOCHEMISTRY; REACTION KINETICS; ULTRAVIOLET RADIATION
Descriptors DEC
CARBOXYLIC ACIDS; CHEMISTRY; ELECTROMAGNETIC RADIATION; HYDROXY ACIDS; KETONES; KINETICS; MAGNETIC RESONANCE; MONOCARBOXYLIC ACIDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; RADIATIONS; RESONANCE

Optional Information

Notes
Published in summary form only.