Published February 2008 | Version v1
Journal article Metadata-only

Synthesis and crystal structure of 4-aminoquinolinium dicitratoborate monohydrate

Creators

  • 1. Inst. Neorganicheskoj Khimii RTU, Riga (Latvia)
  • 2. Latvijskij Inst. Organicheskogo Sinteza, Riga (Latvia)

Description

4-Aminoquinolinium dicitratoborate monohydrate [(4-NH2)C9H6NH][(C6H6O7)2B] · H2O (I) has been synthesized for the first time. Single crystals have been studied by X-ray crystallography. The structural units of crystal I are large complex dicitratoborate anions with a spirane structure, 4-aminoquinolinium cations and crystal water molecules. The crystal packing of I is three-dimensional. Seventeen independent contacts O(N)-H...O and N-H...O, O' form an intricate system of hydrogen bonds

Abstract (Russian)

Впервые синтезирован моногидрат дицитратобората 4-аминохинолиния состава [(4-NH2)C9H6NH][(C6H6O7)2B] · Н2О (I). Получены монокристаллы и проведен полный рентгеноструктурный анализ. Структурные единицы кристалла I - крупные комплексные дицитратоборат-анионы спиранового строения, катионы 4-аминохинолиния и молекулы кристаллизационной воды. Кристаллическая упаковка I трехмерная. Сложную систему водородных связей создают 17 независимых контактов типа O(N)-H...O, N-H...O, О'

Additional details

Additional titles

Original title (Russian)
Синтез и кристаллическая структура моногидрата дицитратобората 4-аминохинолиния

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
53
Journal Issue
2
Journal Page Range
p. 318-327
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
39119775
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; BOND LENGTHS; BORON COMPLEXES; CHEMICAL BONDS; CHEMICAL PREPARATION; CITRATES; HYDRATES; LATTICE PARAMETERS; MOLECULAR STRUCTURE; MONOCRYSTALS; QUATERNARY COMPOUNDS; QUINOLINES; TRICLINIC LATTICES
Descriptors DEC
AMINES; AMMONIUM COMPOUNDS; AROMATICS; AZAARENES; AZINES; CARBOXYLIC ACID SALTS; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DIMENSIONS; HETEROCYCLIC COMPOUNDS; LENGTH; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PYRIDINES; SYNTHESIS

Optional Information

Notes
17 refs., 2 figs., 5 tabs.