Biologically produced sulfur as a novel adsorbent to remove Cd2+ from aqueous solutions

Biological desulfurization processes of landfill gas yield an enormous amount of biologically produced S (BPS) as a byproduct. Capability of BPS to remove Cd²⁺ from aqueous solutions was tested and its removal efficiency was compared to that of granular activated carbon (GAC). Kinetics of Cd²⁺ removal by BPS was a two-stage process with an initial rapid adsorption showing 45% of initial Cd²⁺ was removed within 5 min, followed by a slower adsorption. Cadmium adsorption onto the BPS fitted the Langmuir isotherm model and maximum adsorption capacity of the BPS (63.3 mg g⁻¹) was 1.8 times higher than that of GAC (36.1 mg g⁻¹). Thermodynamic parameters showed that Cd²⁺ adsorption by BPS was favorable and endothermic. Data from XPS proved the main adsorption mechanism to be complexation of Cd²⁺ with sulfides in the BPS. Results demonstrated that BPS can be recycled as a novel adsorbent for Cd²⁺ removal from wastewater.