Photo-, cathodo- and thermoluminescent properties of dysprosium-doped HfO₂ films deposited by ultrasonic spray pyrolysis

In this work, the photoluminescent (PL), cathodoluminescent (CL) and thermoluminescent (TL) properties of hafnium oxide films doped with trivalent dysprosium ions are reported. The films were deposited on glass substrates at temperatures ranging from 300 to 600 °C, using chlorides as precursor reagents. The surface morphology of films showed a veins shaped microstructure at low deposition temperatures, while at higher temperatures the formation of spherical particles was observed on the surface. X-ray diffraction showed the presence of HfO₂ monoclinic phase in the films deposited at temperatures greater than 400 °C. The PL and CL spectra of the doped films showed the highest emission band centered at 575 nm corresponding to the transitions ⁴F_9/2→⁶H_13/2, which is a characteristic transition of Dy³⁺ ion. The greatest emission intensities were observed in samples doped with 1 atomic percent (at%) of DyCl₃ in the precursor solution. Regarding the TL behavior, the glow curve of HfO₂:Dy⁺³ films exhibited spectrum with one broad band centered at about 150 °C. The highest intensity TL response was observed on the films deposited at 500 °C. - Highlights: • Luminescent properties of dysprosium doped hafnium oxide (HfO₂:Dy³⁺) films were analyzed. • HfO₂:Dy³⁺ films were deposited by ultrasonic spray pyrolysis route. • Emission spectra of HfO₂:Dy³⁺ were analyzed by cathode and photoluminescence techniques. • Luminescence mechanism in HfO₂:Dy³⁺ was analyzed. • Results of HfO₂:Dy³⁺ suggest it as a good candidate as UVR dosimeter