Published October 1991 | Version v1
Journal article

Gas chromatographic determination of tributyl phosphate, dibutyl phosphate and butyl phosphate in kerosene solutions

  • 1. Iraq Atomic Energy Commission, Baghdad (Iraq)

Description

A gas chromatographic procedure has been developed for the determination of tributyl phosphate (TBP), dibutyl phosphate (HDBP) and butyl phosphate (H2MBP) in kerosene solutions. The last two compounds were converted into their methyl esters by reaction with a solution of diazomethane in diisopropyl ether prior to analysis. The same procedure was applied to the determination of HBDP and H2MBP produced from gamma irradiation of the 30% TBP-kerosene-3 mol dm-3 HNO3 system. (author)

Additional details

Publishing Information

Journal Title
Analyst
Journal Volume
116
Journal Issue
10
Series
Analyst.
Journal Page Range
1067-1069
ISSN
0003-2654
CODEN
ANALA

INIS

Country of Publication
United Kingdom
Country of Input or Organization
United Kingdom
INIS RN
23014081
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
DBP; GAS CHROMATOGRAPHY; MBP; METHYLATION; TBP
Descriptors DEC
BUTYL PHOSPHATES; CHEMICAL REACTIONS; CHROMATOGRAPHY; ESTERS; ORGANIC COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; PHOSPHORIC ACID ESTERS; SEPARATION PROCESSES