Beryllium in river baseflow, shallow groundwaters and major aquifers of the U.K

Out of 924 samples from 13 aquifer units in the United Kingdom, Be was detected in only 12. In carbonate aquifers no Be was found above the detection limit of 0.05 μg/1. The occurrence of Be was restricted to arenaceous aquifers where concentrations up to 1 μg/1 were found mainly in the Carboniferous Millstone Grit and Lower Cretaceous Lower Greensand. Interstitial water profiles from the unsaturated zones of the Lower Greensand and Triassic sandstone contain Be concentrations in excess of 10 μg/1 within the top 10 m which may persist to the water table at concentrations near to 1 μg/1. The only major anomaly to be found in river baseflow was from the Mourne Mountains of Northern Ireland where Be concentrations of up to 4.7 μg/1 were found associated with the outcrop of the Tertiary granite intrusion. Elsewhere, Be (0.22 μg/1) was found in neutral groundwaters derived from granite feeding the acid Loch Fleet (southern Scotland) in which concentrations of 0.09 μg/1 were maintained. Beryllium occurrence therefore depends strongly on geology. The predominant aqueous species below pH 5.5 is Be2+ and above this Be(OH)+ dominates. The presence of high Al in most waters sampled greatly suppresses the formation of BeF complex ions. Beryllium shows close geochemical behaviour with Mg across a range of pH which may have environmental consequences, if Be substitution for Mg takes place. (author)