Concentrations, physico-chemical states and mean residence times of 210Pb and 210Po in marine and estuarine waters

The concentrations and physico-chemical states of 210Pb have been measured in Bikini Atoll and Washington State coastal waters, and 210Po in Washington coastal waters. Lead-210 concentrations of 113 and 133 dpm.m-3 were found in surface water collections near Bikini Atoll and 29 to 153 dpm.m-3 in Bikini Lagoon. The concentrations of 210Pb in and near Bikini and in Washington State waters increased with depth in the upper 150 m at a rate of 0.35 to 0.45 dpm.m -3.m-1. On the North Equatorial Current waters near Bikini Atoll 210Pb was found associated predominantly with the soluble (colloidal) fraction, but in Washington coastal waters 210Pb and 210Po were found associated with the particulate (> 0.3 μm) fraction. The mean residence times of 210Pb, calculated from the atmospheric input to marine waters from precipitation and the concentrations measured in surface water, were consistent with the physico-chemical states of 210Pb found in samples collected in deep ocean and coastal waters. Approximate values of the mean residence times were calculated, for the upper 50 m, to be as follows: 58 days in the Strait of Juan de Fuca, 128 days at the 5-mile (8 km) station off Cape Flattery (Washington), 163 days at the 12-mile (19 km) station off Cape Flattery, and 2.6 yr near Bikini Atoll. It appears that 210Pb and 210Po can be used to trace particle removal rates in the upper layers of marine waters. (author)