Published June 15, 2019 | Version v1
Journal article Metadata-only

Relation of the phase transition and electrical, photoluminescence properties in (1 − x) Na0.5K0.5NbO3–xLiSbO3:0.006Dy3+ lead free ceramics

Creators

  • 1. Qilu University of Technology (Shandong Academy of Sciences), Key Laboratory of Processing and Testing Technology of Glass & Functional Ceramics of Shandong Province, School of Materials Science and Engineering (China)
  • 2. Nanjing University of Science and Technology, School of Materials Science and Engineering (China)
  • 3. Shaanxi Normal University, School of Materials Science and Engineering (China)

Description

The (1 − x) Na0.5K0.5NbO3–xLiSbO3:0.006Dy3+ were synthesized by a solid state reaction method. The phase structure, microstructure and electric properties were systematically investigated. The orthorhombic–tetragonal (O–T) phase was identified in the composition of x = 0.04 with the help of Raman spectra and photoluminescence response. The ceramic with x = 0.04 mol% LiSbO3 demonstrates optimal properties: Pr = 32.2 μC/cm2, Ec = 12.26 kV/cm, TC = 325 °C, tan δ ≤ 1.5% (250–400 °C). We believe that this work can provide an effective method to investigate the phase transition near polymorphic phase transition (PPT) region. The advantages of simple operation, quick response and pollution-free make it potential to be used in investigating the phase transition near the PPT region of lead-free ceramics.

Additional details

Identifiers

DOI
10.1007/s10854-019-01394-x;

Publishing Information

Journal Title
Journal of Materials Science. Materials in Electronics
Journal Volume
30
Journal Issue
11
Journal Page Range
p. 10507-10515
ISSN
0957-4522
CODEN
JSMEEV

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
52019010
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
CERAMICS; ELECTRICAL PROPERTIES; ORTHORHOMBIC LATTICES; PHASE TRANSFORMATIONS; PHOTOLUMINESCENCE; RAMAN SPECTRA; TANTALUM NITRIDES
Descriptors DEC
CRYSTAL LATTICES; CRYSTAL STRUCTURE; EMISSION; LUMINESCENCE; NITRIDES; NITROGEN COMPOUNDS; PHOTON EMISSION; PHYSICAL PROPERTIES; PNICTIDES; REFRACTORY METAL COMPOUNDS; SPECTRA; TANTALUM COMPOUNDS; THREE-DIMENSIONAL LATTICES; TRANSITION ELEMENT COMPOUNDS

Optional Information

Copyright
Copyright (c) 2019 Springer Science+Business Media, LLC, part of Springer Nature