Published June 21, 1985
| Version v1
Journal article
A simple iterative solution of the Schroedinger equation in matrix representation form
Creators
- 1. Instituto de Investigaciones Fisicoquimicas Teoricas y Aplicadas (INIFTA), La Plata (Argentina). Div. Quimica Teorica
Description
A simple procedure for solving the Schroedinger equation is presented. It is based upon an iterative solution of the secular equation. A large enough convergence rate is obtained by using a basis set of properly scaled functions. The effect of the scaling parameter on the convergence rate is studied in order to improve the calculation. The method is applied to simple, though non-trivial, quantum mechanical models such as the quartic, sextic and octic anharmonic oscillators, a double well potential, and the linear confining potential. Highly accurate eigenvalues for all values of the coupling parameter are obtained. (author)
Additional details
Publishing Information
- Journal Title
- J. Phys., A (London). Math. Gen.
- Journal Volume
- 18
- Journal Issue
- 9
- Series
- J. Phys., A (London). Math. Gen.
- Journal Page Range
- 1389-1398
- ISSN
- 0305-4470
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 16062048
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- ANALYTICAL SOLUTION; ANHARMONIC OSCILLATORS; CONVERGENCE; EIGENVALUES; EXCITED STATES; HAMILTONIANS; ITERATIVE METHODS; MATRICES; POTENTIALS; QUANTUM MECHANICS; SCALING LAWS; SCHROEDINGER EQUATION; SECULAR EQUATION
- Descriptors DEC
- DIFFERENTIAL EQUATIONS; ENERGY LEVELS; EQUATIONS; MATHEMATICAL OPERATORS; MECHANICS; PARTIAL DIFFERENTIAL EQUATIONS; QUANTUM OPERATORS; WAVE EQUATIONS