Published September 1990 | Version v1
Journal article Metadata-only

Study of different-ligand complexes of zinc(2), cadmium(2) and mercury(2) diethyldithiocarbamates with nitrogen-containing heterocycles by means of IR- and NMR-spectroscopy

Creators

  • 1. AN SSSR, Novosibirsk (USSR). Inst. Neorganicheskoj Khimii

Description

New mixed-ligand complexes with ML2A composition, where L=(C2H5)2NCS2-, M=Zn2+, Cd2+ (A=Phen, Bipy) and also HgL2Phen have been prepared. 1H, 14N, 113Cd NMR-spectra of their solutions in CHCl3 (CDCl3) and IR-spectra of solid samples in the region of metal-ligand vibrations have been examined. It has been shown that there are bidentate coordinations of L, Phen, Bipy both in solid complexes and in solutions; complexes are slightly dissociated in solutions

Additional details

Additional titles

Original title (Russian)
Изучение разнолигандных комплексов диэтилдитиокарбаматов цинка(2), кадмия(2) и ртути(2) с азоцодержащими гетероциклами методами IK- и YaMR-спектроскопии

Publishing Information

Journal Title
Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk
Journal Issue
no.1
Series
Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk.
ISSN
0002-3426
CODEN
IZSKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
22071440
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BIPYRIDINES; CADMIUM COMPLEXES; CHEMICAL PREPARATION; CHLOROFORM; DEDTC; INFRARED SPECTRA; MOLECULAR STRUCTURE; NMR SPECTRA; PHENANTHROLINE-ORTHO; SOLIDS; SOLUTIONS
Descriptors DEC
AZINES; CARBAMATES; CARBONIC ACID DERIVATIVES; CARBOXYLIC ACID SALTS; CHELATING AGENTS; COMPLEXES; DISPERSIONS; HETEROCYCLIC COMPOUNDS; HOMOGENEOUS MIXTURES; MIXTURES; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; PHENANTHROLINES; PYRIDINES; REAGENTS; SPECTRA; SYNTHESIS