Published September 1978
| Version v1
Journal article
Photochemical generation of metastable methylcopper complexes. Oxidation-reduction of methyl radicals by copper complexes
Description
Methyl radicals, generated by flash irradiations of Co(NH3)5OCOCH32+, were intercepted with Cu2+(aq) and Cu+(aq) ions. Metastable species, formed in these reactions, were assigned as CuCh32+ (lambda/sub max/ less than or equal to 350 nm) and CuCH3+ (lambda/sub max/370 nm). A transient, assigned also as CuCH3+, was observed in irradiations of CuOCOCH3+. Product yields were measured in order to confirm the nature of the transients. 1 table, 2 figures
Additional details
Publishing Information
- Journal Title
- Inorg. Chem.
- Journal Volume
- 17
- Journal Issue
- 9
- Series
- Inorg. Chem.
- Journal Page Range
- 2506-2508
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 10444013
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CARBON DIOXIDE; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; COBALT; COBALT COMPLEXES; COPPER; COPPER COMPLEXES; ETHANE; GAS CHROMATOGRAPHY; MASS SPECTRA; METHANE; METHANOL; METHYL RADICALS; OXIDATION; PERCHLORIC ACID; PHOTOCHEMISTRY; PHOTOLYSIS; REDUCTION
- Descriptors DEC
- ALCOHOLS; ALKANES; ALKYL RADICALS; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHEMICAL REACTIONS; CHEMISTRY; CHLORINE COMPOUNDS; CHROMATOGRAPHY; COMPLEXES; DECOMPOSITION; DISPERSIONS; ELEMENTS; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROXY COMPOUNDS; INORGANIC ACIDS; KINETICS; METALS; MIXTURES; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; RADICALS; REACTION KINETICS; SEPARATION PROCESSES; SOLUTIONS; SPECTRA; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENTS