Published April 11, 1978
| Version v1
Journal article
The 121Sb Moessbauer effect in the mixed valence phases M2sub(0.5)sup(I)SbMsub(0.5)sup(IV)Cl6 (Msup(I)=NH4, Rb or Cs, Msup(IV)=Se, Te or Sn)
Description
The Sb-121 Moessbauer spectra of the title compounds show the presence of both Sb(III) and Sb(V) sites. The chemical isomer shifts can best be explained in terms of loss of Sb(III) s-electron density to solid state bands. The Moessbauer parameters for the solid solutions studied are tabulated and can be compared with the data for other mixed valence antimony halides. (T.I.)
Additional details
Publishing Information
- Journal Title
- Radiochem. Radioanal. Lett.
- Journal Volume
- 33
- Journal Issue
- 3
- Series
- Radiochem. Radioanal. Lett.
- Journal Page Range
- 219-224
- ISSN
- 0079-9483
INIS
- Country of Publication
- Hungary
- Country of Input or Organization
- Hungary
- INIS RN
- 9415417
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- ANTIMONY COMPOUNDS; ANTIMONY 121; CHEMICAL SHIFT; COMPARATIVE EVALUATIONS; DATA; MOESSBAUER EFFECT; SOLID SOLUTIONS; VALENCE
- Descriptors DEC
- ANTIMONY ISOTOPES; DISPERSIONS; HOMOGENEOUS MIXTURES; INFORMATION; INTERMEDIATE MASS NUCLEI; ISOTOPES; MIXTURES; NUCLEI; ODD-EVEN NUCLEI; SOLUTIONS; STABLE ISOTOPES
Optional Information
- Notes
- 9 refs.; 2 tabs.