Facile conversion of kaolinite into clay nanotubes (KNTs) of enhanced adsorption properties for toxic heavy metals (Zn2+, Cd2+, Pb2+, and Cr6+) from water

Highlights: • KNTs was synthesized as multi-walled tubes with 105 m²/g surface area and 12 nm pore diameter. • KNTs show uptake capacities of 103 mg/g (Zn²⁺), 116 mg/g (Cd²⁺), 91 mg/g (Cr⁶⁺) and 89 mg/g (Pb²⁺). • The equilibrium was achieved after 120 min (Cr⁶⁺), 240 min (Zn²⁺) and 360 min (Cd²⁺ and Pb²⁺). • KNTs are of better adsorption capacity than several kaolinite and CNTs based adsorbents. • They were used successfully in the purification of tap water, groundwater and sewage water. -- Abstract: Kaolinite nanotubes (KNTs) were synthesized from kaolinite by ultrasonic scrolling and characterized using X-ray diffractometer, scanning and transmission electron microscopes; and FTIR-FT Raman spectrometer. The synthetic KNTs appear as multi-walled scrolls of 12 nm average pore diameter and 50–600 nm particle length; and exhibit surface area of 105 m²/g. KNTs were used as adsorbents for Zn²⁺, Cd²⁺, Pb²⁺, and Cr⁶⁺ with uptake capacities of 103 mg/g, 116 mg/g, 89 mg/g, and 91 mg/g, respectively. The equilibration time of Cd²⁺ and Pb²⁺ adsorption is 360 min and for Cr⁶⁺ and Zn²⁺ area 120 min and 240 min, respectively. KNTs adsorption systems can be described mainly by Lagergren-second order and Freundlich models (R²> 0.95) as kinetic and isotherm models. This reflected multilayer adsorption forms with chemical sharing or ion exchange processes. KNTs exhibits high reusability and used for five cycles in the removal of the studied metals (100 mg/L). The removal percentages declined by 20.5%, 15.12%, 22.8% and 23.16% with repeating the reused cycles from cycle 1 to cycle 5 for Zn²⁺, Cd²⁺, Pb²⁺, and Cr⁶⁺, respectively. KNTs were applied successfully in realistic purification of tap water, groundwater, and sewage water from the inspected metals.