Influence of Al(III) and Sb(V) on the transformation of ferrihydrite nanoparticles: Interaction among ferrihydrite, coprecipitated Al(III) and Sb(V)

Highlights: • Coprecipitated Al(III) inhibited the transformation of ferrihydrite. • The presence of Al(III) increased the precipitation of Sb(V). • The fate of Sb(V) was affected by the Al(III) and transformation of ferrihydrite. • The Sb(V) enhanced the transformation of Al-coprecipitated ferrihydrite. • Al(III) and Sb(V) had a competitive substitution for lattice Fe of ferrihydrite. Ferrihydrite is ubiquitous in natural environments and is usually co-precipitated with impure ions and toxic contaminants like Al(III) and Sb(V) during the neutralization process of acid mine drainage. However, little is known about the dynamic interactions among ferrihydrite, Al(III) and Sb(V). In this study, the influence of coprecipitated Al(III) and Sb(V) on the transformation of ferrihydrite was investigated. The samples were characterized by X-ray diffraction (XRD), Raman spectroscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and transmission electron microscopy before and after aging for 10 days at 70 °C. Results indicated that the Al(III) enhanced the immobilization of Sb(V) under neutral and alkaline conditions, and the presence of Sb(V) induced more production of extractable Al(III). XRD patterns revealed that the transformation rate of coprecipitated Al(III) and Sb(V) ferrihydrite was higher than Al-coprecipitated ferrihydrite. It is speculated that the presence of Sb(V) weakened the inhibition of Al(III) under experimental conditions. Competitive reaction of Al(III) and Sb(V) for substitution on the lattice Fe of ferrihydrite, likely decreased Al(III) substitution on ferrihydrite, and thus increased the observed transformation rate of ferrihydrite. These results have significant environmental implications for predicting the role of impurities and contaminants on ferrihydrite transformation processes.