Published April 1982
| Version v1
Journal article
On reactions in three-component system lanthanide halide-electro triisobutylaluminium
Description
The methods of infrared spectroscopy have been used to show that complexing takes place by oxygen atom of phosphoryl or sulphoxide group at the interaction between NdCl3 and tributylphosphate (TBP), NdCl3 and diamylsulphoxide, triisobutylaluminium (TIBA) and TBP. Thermal effect of the interaction reaction between TIBA and TBP is calculated; it is established that the addition products have the composition 1:1 and form at TIBA excess. The value of the thermal effect of the interaction reaction in the NdCl3x3TBP-TIBA system depends on ratio Nd:Al; in the interaction products the ratio is Nd:Al=1=2
Additional details
Additional titles
- Original title (Russian)
- О взаимодействиях в трехкомпонентной системе галогенид лантаноида-электронодонор-триизобутилалюминий
- Augmented title (English)
Publishing Information
- Journal Title
- Izv. Akad. Nauk SSSR, Ser. Khim.
- Journal Issue
- no.4
- Series
- Izv. Akad. Nauk SSSR, Ser. Khim.
- ISSN
- 0002-3353
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 14753826
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALUMINIUM COMPOUNDS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHLORIDES; DMSO; FORMATION HEAT; INFRARED SPECTRA; NEODYMIUM COMPLEXES; ORGANOMETALLIC COMPOUNDS; TBP
- Descriptors DEC
- BUTYL PHOSPHATES; CHLORINE COMPOUNDS; COMPLEXES; ENTHALPY; ESTERS; HALIDES; HALOGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; ORGANIC SULFUR COMPOUNDS; PHOSPHORIC ACID ESTERS; PHYSICAL PROPERTIES; RARE EARTH COMPLEXES; REACTION HEAT; SPECTRA; SULFOXIDES; SYNTHESIS; THERMODYNAMIC PROPERTIES
Optional Information
- Notes
- For English translation see the journal Bulletin of the Academy of Sciences USSR, Division of Chemical Science (USA).