Published January 2016 | Version v1
Journal article

A mixed quantum-classical description of pheophorbide a linear absorption spectra: Quantum-corrections of the Q y - and Q x -absorption vibrational satellites

  • 1. Institut für Chemie, Universität Potsdam, Karl-Liebknecht-Straße 24-25, D-14476 Potsdam, Federal Republic of (Germany)
  • 2. Institut Lumière Matière, UMR5306 Université Claude Bernard Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France)
  • 3. Institut für Physik, Humboldt-Universität zu Berlin, Newtonstraße 15, D-12489 Berlin, Federal Republic of (Germany)

Description

The ground-state classical path approximation is utilized to compute molecular absorption spectra in a mixed quantum-classical frame. To improve the description for high-frequency vibrational satellites, related quantum correction factors are introduced. The improved method is demonstrated for the Qy- and Qx-bands of pheophorbide a.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.cplett.2015.11.016

Additional details

Identifiers

DOI
10.1016/j.cplett.2015.11.016;
PII
S0009261415008672;

Publishing Information

Journal Title
Chemical Physics Letters
Journal Volume
643
Journal Page Range
p. 61-65
ISSN
0009-2614
CODEN
CHPLBC

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
51123609
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ABSORPTION SPECTRA; GROUND STATES; SATELLITES
Descriptors DEC
ENERGY LEVELS; SPECTRA

Optional Information

Copyright
Copyright (c) 2015 Elsevier B.V. All rights reserved.