Published February 1996
| Version v1
Journal article
Volumetric properties of mixtures of water and methanol-H/D-Isotopmers between 5 and 45 degrees C
Creators
- 1. Institute of Non-Aqueous Solutions Chemistry, Inanovo (Russian Federation)
Description
Densities of H/D-isotopomers mixtures of water (H2O, D2O) and methanol (CH3,OH, CD3OH, CH3OD, and CD3OD) over the full range of compositions were measured at 5, 15, 25, 35, and 45 degrees C. Results have been used to calculate molar volumes, excess molar volumes, apparent molar volumes, and isotope effects of the mixtures. The volumetric properties are discussed in terms of the structural changes in water-methanol solutions under the influence of isotope substitution
Additional details
Publishing Information
- Journal Title
- Journal of Solution Chemistry
- Journal Volume
- 25
- Journal Issue
- 2
- Journal Page Range
- p. 191-201.
- ISSN
- 0095-9782
- CODEN
- JSLCAG
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 27067494
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- DENSITY; DEUTERIUM COMPOUNDS; ISOTOPE EFFECTS; METHANOL; MIXTURES; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE 0273-0400 K; WATER
- Descriptors DEC
- ALCOHOLS; DISPERSIONS; HYDROGEN COMPOUNDS; HYDROXY COMPOUNDS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; TEMPERATURE RANGE