Published January 2019 | Version v1
Journal article

Thermal Decomposition of N-[2,2-Bis(methoxy-NNO-azoxy)ethyl]-4-Nitropyrazole

  • 1. Russian Academy of Sciences, Institute of Problems of Chemical Physics (Russian Federation)

Description

The thermal decomposition of high-energy N-[2,2-bis(methoxy-NNO-azoxy)ethyl]-4-nitropyrazole is studied and the composition of the products formed is determined using differential scanning calorimetry, thermogravimetry, mass spectrometry, and IR spectroscopy. Its heat of melting, as well as the heat and energy of activation and the preexponential factor for its thermal decomposition, have been determined. The mechanism of the process is discussed. It is shown that introducing a nitropyrazole fragment into a diazene oxide molecule does not lead to a decrease in its thermal stability.

Additional details

Identifiers

Publishing Information

Journal Title
Russian Journal of Physical Chemistry B
Journal Volume
13
Journal Issue
1
Journal Page Range
p. 62-67
ISSN
1990-7931

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Copyright
Copyright (c) 2019 Pleiades Publishing, Ltd.