Published January 2019
| Version v1
Journal article
Thermal Decomposition of N-[2,2-Bis(methoxy-NNO-azoxy)ethyl]-4-Nitropyrazole
- 1. Russian Academy of Sciences, Institute of Problems of Chemical Physics (Russian Federation)
Description
The thermal decomposition of high-energy N-[2,2-bis(methoxy-NNO-azoxy)ethyl]-4-nitropyrazole is studied and the composition of the products formed is determined using differential scanning calorimetry, thermogravimetry, mass spectrometry, and IR spectroscopy. Its heat of melting, as well as the heat and energy of activation and the preexponential factor for its thermal decomposition, have been determined. The mechanism of the process is discussed. It is shown that introducing a nitropyrazole fragment into a diazene oxide molecule does not lead to a decrease in its thermal stability.
Additional details
Identifiers
Publishing Information
- Journal Title
- Russian Journal of Physical Chemistry B
- Journal Volume
- 13
- Journal Issue
- 1
- Journal Page Range
- p. 62-67
- ISSN
- 1990-7931
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 52038294
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CALORIMETRY; INFRARED SPECTRA; KINETICS; MASS SPECTROSCOPY; MELTING; MOLECULES; OXIDES; PYROLYSIS; THERMAL GRAVIMETRIC ANALYSIS
- Descriptors DEC
- CHALCOGENIDES; CHEMICAL ANALYSIS; CHEMICAL REACTIONS; DECOMPOSITION; GRAVIMETRIC ANALYSIS; OXYGEN COMPOUNDS; PHASE TRANSFORMATIONS; QUANTITATIVE CHEMICAL ANALYSIS; SPECTRA; SPECTROSCOPY; THERMAL ANALYSIS; THERMOCHEMICAL PROCESSES
Optional Information
- Copyright
- Copyright (c) 2019 Pleiades Publishing, Ltd.