Saturated NHC derived dichalcogen dications

Herein, the synthesis and characterization of dicationic dichalcogenide compounds [(SIPr)E]${}_2$(OTf)${}_2$ (3a-E) (E = S, Se, Te) based on a saturated N-heterocyclic carbene (NHC), SIPr [SIPr = C{N(Dipp)CH${}_2$}${}_2$, Dipp = 2,6‐iPr${}_2$C${}_6$H${}_3$] are reported. Treatment of SIPr (1a) with elemental chalcogens affords the heavier ketone derivatives (SIPr)E (2a-E), which readily undergo oxidative E-E coupling reactions with triflic anhydride to yield the corresponding products 3a-E. Compounds 3a-E are air-stable crystalline solids and were characterized by NMR and UV/Vis spectroscopy as well as by X-ray diffraction methods. (© 2020 The Authors. Published by Wiley‐VCH Verlag GmbH and Co. KGaA.)