Published April 2000 | Version v1
Journal article Metadata-only

Synthesis and characterization of Ru(II) arene complexes, [Ru(η6-arene)(dppm)H]+(η6-arene=benzene, p-cymene or hexamethyl-benzene), [Ru(η6-arene)(py)3]2+ and [Ru(η6-arene)(py)2Cl]+

Creators

  • 1. Dept. of Chemistry, A.P.S. University, Rewa (India)

Description

Reactions of [(Ru(η6-arene)Cl2)2] (η6-arene = benzene, p - cymene, hexamethylbenzene) in methanol, in presence of AgBF4/AgPF6 with 1,2-bis(diphenylphosphino)methane (dppm) cationic hydrido complexes [Ru(η6-arene)(dppm)H]+. However, under similar and some changed conditions, reaction pyridine result in the formation of [Ru(η6-arene)(py)3]2+ and [Ru(η6-arene)(py)2Cl]+. The reaction products have been characterized by elemental analyses, IR, 1H, 31P NMR and FAB mass spectra. (author)

Additional details

Publishing Information

Journal Title
Indian Journal of Chemistry. Section A: Inorganic, Bio-inorganic, Physical, Theoretical and Analytical Chemistry
Journal Volume
39
Journal Issue
4
Journal Page Range
p. 453-456
CODEN
ICACEC

INIS

Country of Publication
India
Country of Input or Organization
India
INIS RN
32021633
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; INFRARED SPECTRA; MASS SPECTRA; NMR SPECTRA; PYRIDINES; RUTHENIUM COMPLEXES; STABILITY
Descriptors DEC
AZINES; COMPLEXES; HETEROCYCLIC COMPOUNDS; KINETICS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; REACTION KINETICS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
15 refs., 2 tabs.