Published June 2013
| Version v1
Journal article
Cycloaddition and Crosslinking Reactions of CO2 and Glycidyl Methacrylate using Ionic Liquid
- 1. Kongju National University, Cheonan (Korea, Republic of)
Description
In this study the cycloaddition of glycidyl methacrylate (GMA) and CO2 using ionic liquid as catalyst was performed for the technology of CO2 reduction. The structure of synthesized cyclic carbonate, [2-oxo-1,3-dioxolan-4-yl]methacrylate (DOMA) was analyzed and confirmed by FT-IR and 1H-NMR. The change in conversion with respect to reaction time was investigated using 1H-NMR. Interestingly, the ionic polymerization of vinyl groups and crosslinking reaction between cyclic carbonate rings of DOMA were observed following completion of cycloaddition
Additional details
Publishing Information
- Journal Title
- Korean Chemical Engineering Research
- Journal Volume
- 51
- Journal Issue
- 3
- Series
- 15 refs, 9 figs, 1 tab
- Journal Page Range
- p. 342-346
- ISSN
- 2233-9558
INIS
- Country of Publication
- Korea, Republic of
- Country of Input or Organization
- Korea, Republic of
- INIS RN
- 46084582
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CARBON DIOXIDE; CARBONATES; CATALYSTS; CONVERSION; METHACRYLATES; NMR IMAGING; POLYMERIZATION; REDUCTION
- Descriptors DEC
- CARBON COMPOUNDS; CARBON OXIDES; CARBOXYLIC ACID SALTS; CHALCOGENIDES; CHEMICAL REACTIONS; DIAGNOSTIC TECHNIQUES; OXIDES; OXYGEN COMPOUNDS