Published 1990 | Version v1
Journal article

Study of reaction kinetics of H atoms with actinoid ions in acidic aqueous solutions using pulsed radiolysis method

Description

By the method of pulsed radiolysis (irradiation by 5 MeV electrons) rate constants (k) of H atom reaction with Pu4+, Pu6+, Pu3+, Np4+, Np3+, U6+, U4+ ions in HClO4 and H2SO4 solutions by competing reaction of H atom with benzoic acid, methylene blue or IrCl62-, have been evaluated. It is ascertained that in the series U6+, Np6+, Pu6+ a dependence between k and E6+/5+0 is observed. In HClO4 rate constants are an order lower than in H2SO4

Additional details

Additional titles

Original title (Russian)
Исследование кинетики реакций атомов Х с ионами актиноидов в кислых водных растворах методом импульсного радиолиза

Publishing Information

Journal Title
Radiokhimiya
Journal Volume
32
Journal Issue
4
Series
Radiokhimiya.
Journal Page Range
123-126
ISSN
0033-8311
CODEN
RADKA