Published 1961 | Version v1
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Mechanism of Prototropy. III. Kinetics of the Tautomerization of Benzylidene-Benzylamine. comparison of the influence of hydrogen and alkyl groups on the SE2' reaction rate

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Description

The rate of the proto tropic change of benzylidene-benzylamine has been determined by using azomethine 14C-labelled in the methylenic group and measuring the distribution of activity between benzaldehyde and benzylamine obtained by hydrolysis at different reaction times. this rate has been compared with those of tautomerization of benzylidene-α-alkyl benzylamine and α-alkyl benzylidene-benzyl amines in the same experimental conditions in order to establish ethe influence of alkyl group on this reaction. (Author) 14 refs

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Available from INIS in electronic form

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Additional details

Additional titles

Original title (Spanish)
mecanismo de la Prototropia. III. Cinetica de la tautomerizacion de la benciliden-bencilamina. Comparacion de la influencia del hidrogeno y grupos alcohilos sobre la velocidad de la reaccion S

Publishing Information

Imprint Pagination
24 p.
Report number
JEN--69

INIS

Country of Publication
Spain
Country of Input or Organization
Spain
INIS RN
40092391
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALKYL BENZENESULFONATES; BENZENE; HYDROGEN; HYDROLYSIS; KINETICS; RADIONUCLIDE KINETICS; REACTION KINETICS
Descriptors DEC
AROMATICS; CHEMICAL REACTIONS; DECOMPOSITION; ELEMENTS; ESTERS; HYDROCARBONS; KINETICS; LYSIS; NONMETALS; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; SOLVOLYSIS; SULFONIC ACID ESTERS