Designs for waveguide and structured photocathodes with high quantum efficiency

Conventional S20 multialkali photocathodes have a wide wavelength coverage from < 200 to > 850 nm, but their high transparency and the surface work function result in low quantum efficiencies at longer wavelengths. Theoretical modelling of the photon and excited electron interactions that define the cathode performance provides a realistic prediction of the measured response. The theory emphasizes that the basic light absorption is strongly sensitive to the cathode thickness, wavelength, polarization and incident angle. Parameters can be selected which predict that even at long wavelengths (e.g. 900 nm), absorption may be increased from ∼1% to ∼100%. Cathode topographies can be designed to exploit these responses and offer increased absorption at the longer wavelengths. Alternative designs, which include waveguiding of light within the cathode window, or in structured surfaces, can similarly lead to almost total absorption of the incident light by increasing the number of interactions. These concepts of optimal incidence and waveguiding have been both theoretically modelled and demonstrated in newly fabricated cathode designs. The methods have variously reached quantum efficiencies in excess of 50% at wavelengths in the range from 200 to > 750 nm under different operational conditions. The improvement factors relative to normal incidence on planar cathodes increase for longer wavelengths, and examples of 20-50 times by ∼900 nm were noted. Whilst the absolute S20 efficiency values at long wavelengths are still small, the improvements offer a usable sensitivity even beyond 1 μm, as demonstrated by spectroscopy data up to at least 1140 nm