Published December 1984
| Version v1
Journal article
Arsine oxidation with heteropoly acid in the presence of halide ions
- 1. AN Kazakhskoj SSR, Alma-Ata. Inst. Organicheskogo Kataliza i Ehlektrokhimii
Description
Kinetics and mechanism of arsine oxidation by phosphomolybdovanadium heteropoly acid are studied in the presense of halide ions as catalysts. It is established that intrasphere arsine oxidation in an intermediate V(5) complex with AsH3 and halide-ion is a limiting stage of the proposed mechanism. The quantum-chemical calculation of the electronic structure of intermediate complexes, which supports the above mechanism is carried out. The method of theoretical estimation of the activation energy is proposed
Additional details
Additional titles
- Original title (Russian)
- Окисление арсина гетерополикислотой в присуцтвии галогенид-ионов
Publishing Information
- Journal Title
- Zh. Fiz. Khim.
- Journal Volume
- 58
- Journal Issue
- 12
- Series
- Zh. Fiz. Khim.
- Journal Page Range
- 2975-2979
- ISSN
- 0044-4537
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 16057003
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ACTIVATION ENERGY; ARSENIC HYDRIDES; CATALYSIS; CATALYSTS; CHEMICAL REACTION KINETICS; ELECTRONIC STRUCTURE; HALIDES; HETEROPOLYANIONS; INORGANIC ACIDS; MOLYBDENUM COMPOUNDS; OXIDATION; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; REDUCTION; VANADIUM COMPOUNDS
- Descriptors DEC
- ANIONS; ARSENIC COMPOUNDS; CHARGED PARTICLES; CHEMICAL REACTIONS; COMPLEXES; ENERGY; HALOGEN COMPOUNDS; HYDRIDES; HYDROGEN COMPOUNDS; IONS; KINETICS; REACTION KINETICS; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Notes
- For English translation see the journal Russian Journal of Physical Chemistry (UK).