Synthesis, Characterization and Crystal Structure of (α-Aminopyridine-N)- (5,10,15,20-tetraphenylporphyrinato) Cadmium(II) Acetone Solvate
Creators
- 1. Huaiyin Teachers College, Huaian (China)
- 2. Qingdao University of Science and Technology, Qingdao (China)
Description
The reactivity of synthetic metalloporphyrins with various axial liagnds has also been intensively studied for a few years, since it has been recently shown that anionic ligands of iron (III) porphyrin as well as manganese (III) porphyrin complexes play an important role in the catalytic oxygenation of hydrocarbons. On the other hand, the Cd(II) ion is an important transition metal element and many cadmium(II) porphrin complexes have been studied. However, till now, to the best of our knowledge, the Cd(II) porphhrin complexes having axial ligands are little. Recently, in our laboratory, the title complex of (α-aminopyridine-N)-(5,10,15,20-tetraphenylporphyrinato) cadmium(II) acetone solvate, in which α-aminopyridine is used as an axial ligand, has been synthesized. Natural population analysis on the title complex also has been performed by using density functional theory at B3LYP/LANL2DZ level. Herein, we report the experimental results as well as the theoretical calculated results of the title complex
Additional details
Publishing Information
- Journal Title
- Bulletin of the Korean Chemical Society
- Journal Volume
- 27
- Journal Issue
- 7
- Series
- 13 refs, 2 figs
- Journal Page Range
- p. 1053-1055
- ISSN
- 0253-2964
INIS
- Country of Publication
- Korea, Republic of
- Country of Input or Organization
- Korea, Republic of
- INIS RN
- 49099397
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ACETONE; CADMIUM; COMPUTER CALCULATIONS; CRYSTAL STRUCTURE; DENSITY; REACTIVITY; SYNTHESIS
- Descriptors DEC
- ELEMENTS; KETONES; METALS; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES